Quote:
Originally Posted by Jimmie Arroyo
I started on her shirt which will be grayish-light blue. I don't have anything in that color range, so I experimented throwing some burnt orange first. Should that work, or was that completely stupid of me?
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Absolutely! (will work, that is - not the stupid part...

).
The whole piece seems to be a study in complimentary colors of blue & orange. The burnt orange in the shirt will add a lot of depth, especially if you scumble over it with different shades of blue.
In the smidgen of reference photo that we can see - you've got the exact opposite effect on the top of her hair - that beautiful blue refected light will perfectly mirror what you've got going on in her shirt.
This is a natural progression for your beautiful drawing style.